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Fluorspar (Acidspar ≥ 97% CaF₂ & Metspar)

Acidspar (CaF₂ ≥ 97%) for AHF, LiPF₆ & PVDF battery chemicals; Metspar for steel flux

Fluorspar (calcium fluoride, CaF₂) is the foundational, non-substitutable source of fluorine for the global chemical, semiconductor, and clean energy sectors. The international trade splits sharply at 97% CaF₂ purity: Acid-Grade Fluorspar (Acidspar, HS 2529.22) is a refined flotation concentrate containing ≥ 97.0% CaF₂, functioning as the sole commercial precursor for Anhydrous Hydrofluoric Acid (AHF). Metallurgical-Grade Fluorspar (Metspar, HS 2529.21) assays at 75–85% CaF₂ as coarse gravel or briquettes, functioning as a slag fluidizer and dephosphorizing/desulphurizing flux in Basic Oxygen Furnace (BOF) and Electric Arc Furnace (EAF) steelmaking.

In chemical AHF synthesis (Buss-Luwa rotary kiln process at 200–300 °C: CaF₂ + H₂SO₄ → 2HF + CaSO₄), practical operating factors dictate that producing 1.0 MT of AHF requires 2.15 to 2.25 MT of dry acidspar and 1.30 MT of concentrated sulphuric acid (generating 3.6–3.8 MT of synthetic anhydrite screed byproduct). Impurities trigger destructive side reactions: every 1.0 MT of silica (SiO₂) destroys 1.33 MT of high-value HF gas by forming volatile silicon tetrafluoride (SiF₄) and fluorosilicic acid while releasing water that strips the protective iron-sulphate passivating layer from the carbon-steel kiln shell, inducing severe electrochemical corrosion. Calcite (CaCO₃) consumes expensive acid parasitically and triggers violent foaming and dust carryover, while arsenic (As) volatilizes into toxic AsF₃ that disqualifies AHF from semiconductor-grade electronic wet chemical lines (SEMI Grade 5 UP-HF).

The global fluorspar balance has undergone a structural inversion: China—historically supplying > 55–60% of world volume—has become a structural net importer (importing over 1.02 million MT of raw fluorspar in 2024 alone to feed its domestic battery and solar manufacturing). Chinese acidspar exports collapsed 77% from 235,684 MT in 2022 to 54,561 MT in 2024, and MOFCOM/GACC reinstated strict export licensing effective 1 January 2026. Concurrently, EV lithium-ion battery demand is exploding: LiPF₆ conducting salt contains 75.0% fluorine by weight (consuming 2.5–2.8 MT acidspar per MT of salt), and PVDF cathode binders and separator coatings consume 150–240 MT acidspar equivalent per GWh of cell production.

To mitigate supply concentration risks, CBIL structures acidspar procurement across tier-1 non-Chinese primary corridors: Mexico's Las Cuevas mine (Koura / Orbia, San Luis Potosí, 280 kt/yr acidspar) evacuated via CPKC rail to dedicated deepwater bulk terminals at the Port of Tampico; South Africa's Bushveld complex (Minersa's Vergenoeg mine, 240 kt/yr, and SepFluor's Nokeng mine, 180 kt/yr) exporting through the Port of Durban and Richards Bay; Spain's Minersa Asturias operations; and Viet Nam's Masan High-Tech Materials Nui Phao polymetallic complex via Port Haiphong. Ocean shipments of acidspar filter cake (8.0%–10.5% moisture) are classified under the IMO IMSBC Code as Group A Cargoes that may liquefy if shipped above their Transportable Moisture Limit (TML); all seaborne parcels carry certified Flow Moisture Point (FMP) and moisture tests completed within 7 days of loading. Parcels move in 15,000–30,000 MT Handysize bulk carriers or in 1,000 kg FIBC bags in 20ft dry containers.

Need the ship as well? Our chartering desk prices bulk limestone, gypsum and aggregates freight on LaycanDesk.

Excluded origins are not offered, including product re-exported, blended or re-processed through a third country. Every lot moves with a certificate of origin naming the producing plant, mine or grower country, and nothing is quoted before the seller and loading point are known.

Indicative reference

$480–$560 (Acidspar dry MT FOB) / $320–$390 (Metspar FOB) USD / MT

as at September 2026

IncotermsFOB · CFR · CIF
OriginsMexico (Koura Las Cuevas via Port of Tampico), South Africa (Minersa Vergenoeg & SepFluor Nokeng via Durban), Spain (Minersa Asturias), Viet Nam (Masan High-Tech Nui Phao via Haiphong), China (strict MOFCOM export licence only)
PackagingBulk Handysize vessels (15,000–30,000 MT, IMSBC Group A certified); 1,000 kg heavy-duty FIBC bags in 20ft containers (20–24 MT per box)
HS Code2529.22 (acidspar ≥ 97%) / 2529.21 (metspar ≤ 97%)

Reference level only — not an offer, and reviewed quarterly. Levels shown are as at September 2026. Firm pricing is quoted per RFQ, subject to volume, terms and inspection.

Mexico (Koura Las Cuevas via Port of Tampico) · South Africa (Minersa Vergenoeg & SepFluor Nokeng via Durban) · Spain (Minersa Asturias) · Viet Nam (Masan High-Tech Nui Phao via Haiphong) · China (strict MOFCOM export licence only)

Typical Specification

CaF₂ Purity (Acidspar)≥ 97.00% min (dry basis; reject if < 96.50%)
Silica (SiO₂)≤ 1.00% max (reject if > 1.20–1.50%; prevents parasitic HF loss)
Calcium Carbonate (CaCO₃)≤ 1.00%–1.50% max (prevents kiln foaming)
Total Sulphur (S)≤ 0.03%–0.05% max
Phosphorus & ArsenicP ≤ 0.020% max; As ≤ 5.0–10.0 ppm max
Moisture & Safety8.0%–10.5% (Filter Cake); IMSBC Group A (TML / FMP certified)
GranulometryAcidspar: 80% passing 75 µm (200 mesh); Metspar: 10–50 mm gravel

Specifications are indicative and adjusted to the agreed contract and destination requirements. Final spec confirmed on COA / SGS.

Available Grades

Acidspar Flotation Filter Cake (≥ 97.0% CaF₂, 8–10% H₂O, IMSBC Group A)Acidspar Thermally Dried Powder (≥ 97.0% CaF₂, H₂O ≤ 0.1%, FIBC Bags)Low-Arsenic Electronic Acidspar (As ≤ 5 ppm, P ≤ 0.010% for UP-HF)Metspar Natural Gravel (75–85% CaF₂, 10–50 mm BOF/EAF Flux)Metspar Screened Briquettes (Custom CaF₂ & Binder Spec)Ceramic / Glass Grade Fluorspar (85–95% CaF₂)

Applications

  • Anhydrous Hydrofluoric Acid (AHF) synthesis (rotary kilns)
  • Lithium-ion battery electrolyte salts (LiPF₆, LiFSI)
  • PVDF fluoropolymer cathode binders & separator coatings
  • Semiconductor wet chemical etching (SEMI Grade 5 UP-HF)
  • Next-generation ultra-low GWP refrigerants (HFO-1234yf / ze)
  • Steelmaking & foundry ladle fluxing (metspar gravel)
  • Primary aluminium smelting (AlF₃ / synthetic cryolite)

Category

Industrial Minerals & Construction

Incoterms

FOB · CFR · CIF

Pricing basis

USD / MT

Inspection

SGS / Intertek at load port

Fluorspar (Acidspar ≥ 97% CaF₂ & Metspar) — buyer questions

Why is silica (SiO₂) capped so strictly in acid-grade fluorspar?

Silica reacts with newly liberated hydrofluoric acid gas in the rotary kiln (SiO₂ + 4HF → SiF₄ + 2H₂O). Every 1.0 MT of silica consumes 1.33 MT of high-value HF gas, converting it into low-value fluorosilicic acid. Furthermore, the generated water dilutes hot sulphuric acid inside the kiln, stripping the protective iron-sulphate passivating coating and causing severe corrosion of the carbon steel kiln shell.

How has the EV battery transition reshaped global fluorspar demand?

Lithium-ion battery manufacturing is the fastest-growing fluorine consumption vector. The primary conducting salt, LiPF₆, contains 75.0% elemental fluorine by weight, requiring 2.5–2.8 MT of high-purity acidspar per MT of salt. Additionally, battery-grade PVDF used as a cathode binder (NMC/LFP) and separator thermal coating requires 150–240 MT of acidspar equivalent per GWh, driving demand independent of traditional steel and refrigerant cycles.

Why has China transitioned from a dominant exporter to a net importer of fluorspar?

Decades of intensive mining depleted China's shallow, high-grade deposits, dropping average run-of-mine grades from > 55% to 30–40% CaF₂. Aggressive environmental and mine safety crackdowns shuttered artisanal mines, while domestic AHF capacity exceeded 4.1 million MT/year to feed internal battery and solar gigafactories. As a result, China imported over 1.02 million MT of raw fluorspar in 2024 and re-instituted export licensing on 1 January 2026.

What safety protocols govern the ocean transport of acidspar filter cake?

Acidspar flotation filter cake (typically 8.0%–10.5% moisture) is classified under the IMO IMSBC Code as a Group A Cargo capable of liquefying if moisture exceeds the Transportable Moisture Limit (TML). Shippers must provide independent certification of Flow Moisture Point (FMP) and moisture testing performed within 7 days of loading. Vessels must be equipped with certified bilge systems, and loading is stopped during rainfall.

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